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<div id="ge0wm2g" class="info text-center"> <div id="usi20ow" class="s">怎么去除電鍍廢水中的次磷至表三標準</div> <div id="aqqoogo" class="x">作者：admin　來源：原創　日期：2015-4-27 23:36:59　人氣：<span id="hits">639</span>　評論：<span><a href='/plug/comment.asp?id=107'>0</a></span></div> </div> <div id="oemuccc" class="my"> <p style="text-indent: 2em;"><span style="font-size: 14px;">一、電鍍廢水次磷的排放標準</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">對于電鍍廢水，國家表二排放標準要求，磷的排放量不高于1mg/L，國家表三排放標準要求，磷的排放量不高于0.5mg/L。新環保法執行以后，長三角地區，珠三角地區已經嚴格執行表三標準，而其他地方也已經逐漸從表二標準過渡到表三標準，處理難度越來越大。</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;"> </span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">二、電鍍廢水次磷的處理難點</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">電鍍廢水處理次磷的難點，在于次磷的特殊性，次磷酸鹽在水溶液中易溶于水，因此投加一般的<a href="http://www.t44867k.cn/show.asp?id=4" title="除磷劑" target="_blank" class="sitelink">除磷劑</a>無法與次磷酸根形成沉淀。同時，如果采用芬頓氧化技術，將次磷氧化為正磷的思路，再加石灰進行沉淀處理，同樣無法處理達標。原因在于芬頓氧化技術的氧化效率有限，只能氧化一部分次磷至正磷，因此廢水中還繼續殘留有次亞磷酸根離子，無法除去，采用芬頓氧化技術和石灰沉淀的辦法只能夠把磷處理至10mg/L左右。</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;"> </span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">三、電鍍廢水次磷的處理原理</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">電鍍廢水除次磷，采用<a href="http://www.t44867k.cn/show.asp?id=4" title="次亞磷去除劑" target="_blank" class="sitelink">次亞磷去除劑</a>P3進行沉淀的原理，<a href="http://www.t44867k.cn/show.asp?id=4" title="次亞磷去除劑" target="_blank" class="sitelink">次亞磷去除劑</a>P3是一種多相無機復合鹽，在廢水中能夠水解成長鏈結構，并帶有大量的正電荷，磷吸附基團，在雙氧水的催化作用下，能夠與次亞磷結合生成沉淀，從而把次亞磷去除。此方法與傳統的氧化沉淀法不同，氧化沉淀法本質上是把次亞磷氧化為正磷，而<a href="http://www.t44867k.cn/show.asp?id=4" title="次亞磷去除劑" target="_blank" class="sitelink">次亞磷去除劑</a>沉淀法是利用<a href="http://www.t44867k.cn/show.asp?id=4" title="次亞磷去除劑" target="_blank" class="sitelink">次亞磷去除劑</a>，直接與次亞磷酸根離子直接生成沉淀。利用此方法步驟簡單，工藝簡單，去除效果好。</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;"> </span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">四、電鍍廢水處理次磷至表三標準的藥劑用量與成本</span></p><p style="text-indent: 2em;"><span style="font-size: 14px;">假設，電鍍廢水中次亞磷含量在100mg/L，那么處理次亞磷至0.5mg/L以下，需要投加<a href="http://www.t44867k.cn/show.asp?id=4" title="次亞磷去除劑" target="_blank" class="sitelink">次亞磷去除劑</a>的用量為磷含量的10倍左右，同時投加雙氧水用量在10倍左右。那么處理磷至表三標準的藥劑成本在4-5元左右。</span></p> <div id="eck2yai" class="text-center more"><a href="/">返回首頁</a></div> </div> <div id="ag2goow" class="pz"> <div id="y2ckssk" class="bq">標簽：<a href='/plug/tags.asp?tag=%E8%A1%A8%E4%B8%89%E6%A0%87%E5%87%86'>表三標準</a><a href='/plug/tags.asp?tag=%E7%94%B5%E9%95%80%E5%BA%9F%E6%B0%B4%E9%99%A4%E6%AC%A1%E4%BA%9A%E7%A3%B7'>電鍍廢水除次亞磷</a><a href='/plug/tags.asp?tag=%E6%AC%A1%E4%BA%9A%E7%A3%B7%E8%B6%85%E6%A0%87'>次亞磷超標</a></div> <div id="iy2yaqq" class="lj">本文鏈接：<a 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